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Science 15 May 2009:
Vol. 324. no. 5929, pp. 924 - 927
DOI: 10.1126/science.1171810

Reports

Observing the Quantization of Zero Mass Carriers in Graphene

David L. Miller,1,* Kevin D. Kubista,1,* Gregory M. Rutter,2 Ming Ruan,1 Walt A. de Heer,1 Phillip N. First,1,{dagger} Joseph A. Stroscio2,{dagger}

Application of a magnetic field to conductors causes the charge carriers to circulate in cyclotron orbits with quantized energies called Landau levels (LLs). These are equally spaced in normal metals and two-dimensional electron gases. In graphene, however, the charge carrier velocity is independent of their energy (like massless photons). Consequently, the LL energies are not equally spaced and include a characteristic zero-energy state (the n = 0 LL). With the use of scanning tunneling spectroscopy of graphene grown on silicon carbide, we directly observed the discrete, non-equally–spaced energy-level spectrum of LLs, including the hallmark zero-energy state of graphene. We also detected characteristic magneto-oscillations in the tunneling conductance and mapped the electrostatic potential of graphene by measuring spatial variations in the energy of the n = 0 LL.

1 School of Physics, Georgia Institute of Technology, Atlanta, GA 30332, USA.
2 Center for Nanoscale Science and Technology, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899, USA.

* These authors contributed equally to this work.

{dagger} To whom correspondence should be addressed: first{at}physics.gatech.edu (P.N.F.); joseph.stroscio{at}nist.gov (J.A.S.)

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Science. ISSN 0036-8075 (print), 1095-9203 (online)