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Science 17 August 2007:
Vol. 317. no. 5840, pp. 932 - 934
DOI: 10.1126/science.1144216

Reports

Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure

Yoichi Kubota,* Kenji Watanabe, Osamu Tsuda, Takashi Taniguchi

Materials emitting light in the deep ultraviolet region around 200 nanometers are essential in a wide-range of applications, such as information storage technology, environmental protection, and medical treatment. Hexagonal boron nitride (hBN), which was recently found to be a promising deep ultraviolet light emitter, has traditionally been synthesized under high pressure and at high temperature. We successfully synthesized high-purity hBN crystals at atmospheric pressure by using a nickel-molybdenum solvent. The obtained hBN crystals emitted intense 215-nanometer luminescence at room temperature. This study demonstrates an easier way to grow high-quality hBN crystals, through their liquid-phase deposition on a substrate at atmospheric pressure.

National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan.

* To whom correspondence should be addressed. E-mail: kubota.yoichi{at}nims.go.jp

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Science. ISSN 0036-8075 (print), 1095-9203 (online)