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Science 18 August 2006:
Vol. 313. no. 5789, pp. 954 - 958
DOI: 10.1126/science.1129660

Reports

Two-Dimensional Nematic Colloidal Crystals Self-Assembled by Topological Defects

Igor Musevic,1,2* Miha Skarabot,1 Uros Tkalec,1 Miha Ravnik,2 Slobodan Zumer2,1

The ability to generate regular spatial arrangements of particles is an important technological and fundamental aspect of colloidal science. We showed that colloidal particles confined to a few-micrometer-thick layer of a nematic liquid crystal form two-dimensional crystal structures that are bound by topological defects. Two basic crystalline structures were observed, depending on the ordering of the liquid crystal around the particle. Colloids inducing quadrupolar order crystallize into weakly bound two-dimensional ordered structure, where the particle interaction is mediated by the sharing of localized topological defects. Colloids inducing dipolar order are strongly bound into antiferroelectric-like two-dimensional crystallites of dipolar colloidal chains. Self-assembly by topological defects could be applied to other systems with similar symmetry.

1 J. Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia.
2 Faculty of Mathematics and Physics, University of Ljubljana, Jadranska 19, 1000 Ljubljana, Slovenia.

* To whom correspondence should be addressed. E-mail: igor.musevic{at}ijs.si

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Science. ISSN 0036-8075 (print), 1095-9203 (online)