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Science 31 October 2003:
Vol. 302. no. 5646, pp. 859 - 862
DOI: 10.1126/science.1088342

Reports

Carbonate Deposition, Climate Stability, and Neoproterozoic Ice Ages

Andy J. Ridgwell,1* Martin J. Kennedy,1 Ken Caldeira2

The evolutionary success of planktic calcifiers during the Phanerozoic stabilized the climate system by introducing a new mechanism that acts to buffer ocean carbonate-ion concentration: the saturation-dependent preservation of carbonate in sea-floor sediments. Before this, buffering was primarily accomplished by adjustment of shallow-water carbonate deposition to balance oceanic inputs from weathering on land. Neoproterozoic ice ages of near-global extent and multimillion-year duration and the formation of distinctive sedimentary (cap) carbonates can thus be understood in terms of the greater sensitivity of the Precambrian carbon cycle to the loss of shallow-water environments and CO2-climate feedback on ice-sheet growth.

1 Department of Earth Sciences, University of California–Riverside, Riverside, CA 92521, USA.
2 Climate and Carbon Cycle ModelingGroup, Lawrence Livermore National Laboratory, 7000 East Avenue, L-103, Livermore, CA 94550, USA.

* To whom correspondence should be addressed. E-mail: andyr{at}citrus.ucr.edu

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