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Science 13 April 2001: Vol. 292. no. 5515, pp. 265 - 267 DOI: 10.1126/science.1059175
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Reports
Using Selective Withdrawal to Coat Microparticles
Itai Cohen,1
Hui Li,2
James L. Hougland,2
Milan Mrksich,2
Sidney R. Nagel1
We report a method that uses the process of selective withdrawal of
one fluid through a second immiscible fluid to coat small particles
with polymer films. Fluid is withdrawn through a tube with its orifice
slightly above a water-oil interface. Upon increasing the flow rate,
there is a transition from a state where only oil is withdrawn to a
state where the water, containing the particles to be coated and
appropriate prepolymer reagents, is entrained in a thin spout along
with the oil. The entrained particles eventually cause the spout
interface to break, producing a thin coat of controllable thickness
around each particle, which can be subsequently polymerized using
chemical reagents, light, or heat. This method allows flexibility in
the chemical composition and thickness of the conformal coatings.
1 James Frank Institute and Department of
Physics,
2 Department of Chemistry, University of
Chicago, Chicago, IL 60637, USA.
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