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Science 9 July 1999: Vol. 285. no. 5425, pp. 233 - 236 DOI: 10.1126/science.285.5425.233
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Reports
All-Polymer Optoelectronic Devices
Peter K. H. Ho,
D. Stephen Thomas,
Richard H. Friend,
Nir Tessler
*
Composites of nanoparticles and conjugated polymers
that exhibit composition-tunable optical constants have been developed for use in semiconducting photonic structures. For example, the 550-nanometer wavelength in-plane refractive index of
poly(p-phenylenevinylene)-silica composites can be tailored over the
range of 1.6 to 2.7, allowing efficient distributed Bragg reflectors
and waveguides to be fabricated. Low levels of chemical doping improve
electrical conductivity through these structures without detriment to
their photonic properties. Exemplifying these concepts, all-polymer
microcavities and microcavity light-emitting diodes were demonstrated.
Appropriate confinement of photons and electron-hole pairs in these
organic semiconductor-based structures can be achieved.
Cavendish Laboratory, Madingley Road, Cambridge CB3 0HE, UK.
*
To whom correspondence should be addressed. E-mail:
nt202{at}phy.cam.ac.uk
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