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Science 26 February 1999:
Vol. 283. no. 5406, pp. 1314 - 1317
DOI: 10.1126/science.283.5406.1314

Reports

The Density of Hydrous Magmatic Liquids

Frederick A. Ochs III, Rebecca A. Lange

Density measurements on several hydrous (<=19 mole percent of H2O) silicate melts demonstrate that dissolved water has a partial molar volume (<A><AC>V</AC><AC>&cjs1171;</AC></A>H2O) that is independent of the silicate melt composition, the total water concentration, and the speciation of water. The derived value for <A><AC>V</AC><AC>&cjs1171;</AC></A>H2O is 22.9 ± 0.6 cubic centimeters per mole at 1000°C and 1 bar of pressure, whereas the partial molar thermal expansivity (partial <A><AC>V</AC><AC>&cjs1171;</AC></A>H2O/partial T) and compressibility (partial <A><AC>V</AC><AC>&cjs1171;</AC></A>H2O/partial P) are 9.5 ± 0.8 × 10-3 cubic centimeters per mole per kelvin and -3.2 ± 0.6 × 10-4 cubic centimeters per mole per bar, respectively. The effect of 1 weight percent dissolved H2O on the density of a basaltic melt is equivalent to increasing the temperature of the melt by ~400°C or decreasing the pressure of the melt by ~500 megapascals. These measurements are used to illustrate the viability of plagioclase sinking in iron-rich basaltic liquids and the dominance of compositional convection in hydrous magma chambers.

Department of Geological Sciences, University of Michigan, Ann Arbor, MI 48109-1063, USA.


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THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
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Constraints on the preeruptive volatile concentrations in the Columbia River flood basalts.
(2002)
Geology 30, 179-182
Determination of the limiting fictive temperature of silicate glasses from calorimetric and dilatometric methods: Application to low-temperature liquid volume measurements.
J. A. Tangeman and R. A. Lange (2001)
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Science. ISSN 0036-8075 (print), 1095-9203 (online)