The Density of Hydrous Magmatic Liquids
Frederick A. Ochs III,
Rebecca A. Lange
Density measurements on several hydrous (
19 mole percent of
H2O) silicate melts demonstrate that dissolved water has a
partial molar volume
(
H2O)
that is independent of the silicate melt composition, the total water
concentration, and the speciation of water. The derived value for
H2O is
22.9 ± 0.6 cubic centimeters per mole at 1000°C and 1 bar of
pressure, whereas the partial molar thermal expansivity
(
H2O/
T)
and compressibility
(
H2O/
P) are 9.5 ± 0.8 × 10
3 cubic centimeters per mole per
kelvin and
3.2 ± 0.6 × 10
4 cubic centimeters per mole
per bar, respectively. The effect of 1 weight percent dissolved
H2O on the density of a basaltic melt is equivalent to
increasing the temperature of the melt by ~400°C or decreasing the
pressure of the melt by ~500 megapascals. These measurements are used
to illustrate the viability of plagioclase sinking in iron-rich
basaltic liquids and the dominance of compositional convection in
hydrous magma chambers.
Department of Geological Sciences, University of Michigan, Ann
Arbor, MI 48109-1063, USA.