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Science 23 May 1997:
Vol. 276. no. 5316, pp. 1217 - 1221
DOI: 10.1126/science.276.5316.1217

Articles

The Early Faint Sun Paradox: Organic Shielding of Ultraviolet-Labile Greenhouse Gases

Carl Sagan, Christopher Chyba

Atmospheric mixing ratios of ~10-5 ± 1 for ammonia on the early Earth would have been sufficient, through the resulting greenhouse warming, to counteract the temperature effects of the faint early sun. One argument against such model atmospheres has been the short time scale for ammonia photodissociation by solar ultraviolet light. Here it is shown that ultraviolet absorption by steady-state amounts of high-altitude organic solids produced from methane photolysis may have shielded ammonia sufficiently that ammonia resupply rates were able to maintain surface temperatures above freezing.

Prior to his death in December 1996, Dr. Sagan directed the Laboratory for Planetary Studies at Cornell University, Ithaca, NY 14853-6801, USA. Dr. Chyba is in the Department of Planetary Sciences, University of Arizona, Tucson, AZ 85721-0092, USA. Final changes in response to editors' and referees' comments were made in this manuscript by Dr. Chyba subsequent to Dr. Sagan's death.


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