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Science 27 October 1995:
Vol. 270. no. 5236, pp. 590 - 593
DOI: 10.1126/science.270.5236.590

Articles

Mechanisms for Lithium Insertion in Carbonaceous Materials

J. R. Dahn (1),  Tao Zheng,  Yinghu Liu,  J. S. Xue

Lithium can be inserted reversibly within most carbonaceous materials. The physical mechanism for this insertion depends on the carbon type. Lithium intercalates in layered carbons such as graphite, and it adsorbs on the surfaces of single carbon layers in nongraphitizable hard carbons. Lithium also appears to reversibly bind near hydrogen atoms in carbonaceous materials containing substantial hydrogen, which are made by heating organic precursors to temperatures near 700°C. Each of these three classes of materials appears suitable for use in advanced lithium batteries.


The authors are in the Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6, Canada.
(1) To whom correspondence should be addressed.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Energetic Iron(VI) Chemistry: The Super-Iron Battery.
S. Licht, B. Wang, and S. Ghosh (1999)
Science 285, 1039-1042
   Abstract »    Full Text »



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