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Science 19 August 1994:
Vol. 265. no. 5175, pp. 1077 - 1078
DOI: 10.1126/science.265.5175.1077

Articles

Single-Crystalline (KC60)n: A Conducting Linear Alkali Fulleride Polymer

S. Pekker 1, A. Jánossy 2, L. Mihaly 3, O. Chauvet 4, M. Carrard 4, and L. Forró 4

1 Research Institute for Solid State Physics, H-525 Budapest, P. O. B. 49, Hungary, and Laboratoire de Physique des Solides Semicrystallins, IGA Department de Physique, Ecole Polytechnique Federale de Lausanne, 1015-Lausanne, Switzerland
2 Research Institute for Solid State Physics, H-1525 Budapest, P. O. B. 49, Hungary, and Institute of Physics of the Technical University, H-1521 Budapest, Hungary
3 Department of Physics, State University of New York at Stony Brook, NY 11794-3800, USA.
4 Laboratoire de Physique des Solides Semicrystallins, IGA Departement de Physique, Ecole Polytechnique Federale de Lausanne, 1015-Lausanne, Switzerland

Single crystals of a linear cycloadduct conducting polymer, (KC60)n, have been grown that are a few tenths of a millimeter in length. Partial oxidation under toluene transformed these crystals into bundles of fibers. The degree of polymerization exceeded 100,000.

Submitted on May 3, 1994
Accepted on July 5, 1994





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