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Science 22 October 1993:
Vol. 262. no. 5133, pp. 545 - 547
DOI: 10.1126/science.262.5133.545
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Articles

On the Thermodynamic Stability of Confined Thin Films Under Shear

Dennis J. Diestler 1, Martin Schoen 2, and John H. Cushman 3

1 Department of Agronomy, University of Nebraska, Lincoln, NE 68583
2 Institut für Theoretische Physik, Technische Universität Berlin, Hardenbergstr. 36, 10623 Berlin, Germany
3 Purdue University, West Lafayette, IN 47907

Thin films of monatomic fluid constrained between two plane-parallel structured solid walls have been modeled by Monte Carlo simulation under conditions (fixed temperature, chemical potential, and normal stress or load) prevailing in high-precision measurements of surface forces. Several states of the film, corresponding to different numbers of layers of fluid parallel with the walls, are generally consistent with these conditions, but only one is thermodynamically stable; the others are metastable. When the walls are properly aligned, epitaxial solid phases are stable. These melt under shear, eventually becoming metastable, whereupon a drainage (or imbibition) transition occurs, leading to a stable phase with fewer (or more) layers.

Submitted on May 18, 1993
Accepted on September 8, 1993


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Confinement-Induced Phase Transitions in Simple Liquids.
J. Klein and E. Kumacheva (1995)
Science 269, 816-819
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