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Science 3 September 1993:
Vol. 261. no. 5126, pp. 1307 - 1310
DOI: 10.1126/science.261.5126.1307

Articles

Lattice Effect of Strong Electron Correlation: Implication for Ferroelectricity and Superconductivity

T. Egami 1, S. Ishihara 1, and M. Tachiki 1

1 Institute for Materials Research, Tohoku University, Sendai 980, Japan

Much theoretical work has been devoted to understanding the role of strong electron correlations in high-temperature superconductivity mainly through magnetic interactions, but the possible role of electron correlation in ferroelectricity of metal oxides has not received attention. Diagonalization of a simple many-body, tight-binding Hamiltonian shows that the electron-lattice interaction is dramatically enhanced in some cases by strong electron correlation because of deformation-induced charge transfer. This effect may be closely related to ferroelectricity and superconductivity in transition metal oxides.

Submitted on May 20, 1993
Accepted on July 28, 1993





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Science. ISSN 0036-8075 (print), 1095-9203 (online)