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Science 30 April 1993:
Vol. 260. no. 5108, pp. 649 - 652
DOI: 10.1126/science.260.5108.649

Articles

Condensed-Matter Energetics from Diatomic Molecular Spectra

In Ho Kim 1, Raymond Jeanloz 2, and Kyu Soo Jhung 3

1 Department of Geology and Geophysics, University of California, Berkeley, CA 94720, and Agency for Defense Development, Yuseong Post Office Box 35, Taejeon 305-600, South Korea
2 Department of Geology and Geophysics, University of California, Berkeley, CA 94720
3 Agency for Defense Development, Yuseong Post Office Box 35, Taejeon 305-600, South Korea

Analyses of molecular spectra and compression data from crystals show that a single function successfully describes the dependence on interatomic separation of both the potential energy of diatomic molecules and the cohesive binding energy of condensed matter. The empirical finding that one function describes interatomic energies for such diverse forms of matter and over a wide range of conditions can be used to extend condensed-matter equations of state but warrants further theoretical study.

Submitted on September 3, 1992
Accepted on February 18, 1993





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