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Science 12 July 1991:
Vol. 253. no. 5018, pp. 395 - 400
DOI: 10.1126/science.253.5018.395
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Articles

Enols and Other Reactive Species

YVONNE CHIANG 1 and A. JERRY KRESGE 1

1 Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A1

Rapid advances in the chemistry of enols and other reactive species have been made possible recently by the development of methods for generating these short-lived substances in solution under conditions where they can be observed directly and their reactions can be monitored accurately. New laboratory techniques are described and a sample of the new chemistry they have made available is provided; special attention is given to ynols and ynamines and the remarkable effects that the carbon-carbon triple bonds of these substances have on their acid-base properties.


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Science. ISSN 0036-8075 (print), 1095-9203 (online)