Note to users. If you're seeing this message, it means that your browser cannot find this page's style/presentation instructions -- or possibly that you are using a browser that does not support current Web standards. Find out more about why this message is appearing, and what you can do to make your experience of our site the best it can be.


Science 23 December 1988:
Vol. 242. no. 4886, pp. 1645 - 1653
DOI: 10.1126/science.242.4886.1645

Articles

Laser Femtochemistry

Ahmed H. Zewail 1

1 Professor of chemistry at the Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena, CA 91125

Femtochemistry is concerned with the very act of the molecular motion that brings about chemistry, chemical bond breaking, or bond formation on the femtosecond (10-15 second) time scale. With lasers it is now possible to record snapshots of chemical reactions with sub-angstrom resolution. This strobing of the transition-state region between reagents and products provides real time observations that are fundamental to understanding the dynamics of the chemical bond.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
4D Visualization of Transitional Structures in Phase Transformations by Electron Diffraction.
P. Baum, D.-S. Yang, and A. H. Zewail (2007)
Science 318, 788-792
   Abstract »    Full Text »    PDF »
Soft X-ray-Driven Femtosecond Molecular Dynamics.
E. Gagnon, P. Ranitovic, X.-M. Tong, C. L. Cocke, M. M. Murnane, H. C. Kapteyn, and A. S. Sandhu (2007)
Science 317, 1374-1378
   Abstract »    Full Text »    PDF »
Cluster Chemistry And Dynamics Special Feature: Dynamics of clusters: From elementary to biological structures.
P.-Y. Cheng, J. S. Baskin, and A. H. Zewail (2006)
PNAS 103, 10570-10576
   Abstract »    Full Text »    PDF »
A SN2 Reaction That Avoids Its Deep Potential Energy Minimum.
L. Sun, K. Song, and W. L. Hase (2002)
Science 296, 875-878
   Abstract »    Full Text »    PDF »
Femtochemistry uncovers the nature of electron transfer reactions.
A. W. Castleman Jr., Q. Zhong, and S. M. Hurley (1999)
PNAS 96, 4219-4220
   Full Text »    PDF »
Observation of coherent reaction dynamics in heme proteins.
L Zhu, J. Sage, and P. Champion (1994)
Science 266, 629-632
   Abstract »    PDF »
Vibrationally coherent photochemistry in the femtosecond primary event of vision.
Q Wang, R. Schoenlein, L. Peteanu, R. Mathies, and C. Shank (1994)
Science 266, 422-424
   Abstract »    PDF »
Ultrafast infrared spectroscopy.
P. Stoutland, R. Dyer, and W. Woodruff (1992)
Science 257, 1913-1917
   Abstract »    PDF »



To Advertise     Find Products


Science. ISSN 0036-8075 (print), 1095-9203 (online)