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Science 13 March 1987:
Vol. 235. no. 4794, pp. 1373 - 1376
DOI: 10.1126/science.235.4794.1373

Articles

Superconductivity at 40 K in the Oxygen-Defect Perovskites La2-xSrxCuO4-y

J. M. TARASCON 1, L. H. GREENE 1, W. R. MCKINNON 1, G. W. HULL 1, and T. H. GEBALLE 1

1 Bell Communications Research, 331 Newman Springs Road, Red Bank, NJ 07701.

Structural, magnetic, and electronic properties of compounds in the series La2-xSrx CuO4-y for 0.05 le x le 1.1, with dgrx = 0.025, were studied. Resistance, susceptibility, Meissner, and shielding measurements have revealed superconductivity among several members of the series. For x = 0.15, the transition temperature Tc, measured at the midpoint of the resistive transition, is a maximum at 39.3 K with a width of 2 K. At other compositions the transition is broader and occurs at a lower temperature. Annealing the x = 0.15 sample in oxygen at 500°C increases Tc to 40.3 K, while annealing at the same temperature under vacuum suppresses the superconductivity. These changes in oxygen content and Tc are reversible.

Submitted on January 21, 1987
Accepted on February 5, 1987


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
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