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Science 13 April 1979:
Vol. 204. no. 4389, pp. 198 - 200
DOI: 10.1126/science.204.4389.198

Articles

Extraction and Analysis of Organic Cations from Acid Solution with Strong Electric Fields and Mass Spectrometry

WOODFIN V. LIGON JR. 1

1 General Electric Company, Corporate Research and Development, Schenectady, New York 12301

High electric fields have been used to extract organic cations from solutions of small organic molecules in polyphosphoric acid. The cations have been analyzed by mass spectrometry. Production of ions by this method is shown to be related to ease of protonation by acid rather than to ionization potential.

Submitted on November 24, 1978
Revised on February 2, 1979


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Molecular Analysis by Mass Spectrometry.
W. V. Ligon Jr. (1979)
Science 205, 151-159
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Science. ISSN 0036-8075 (print), 1095-9203 (online)