Hydroxyl Radical Reactivity with Diethylhydroxylamine
R. A. GORSE JR. 1,
R. R. LII 1, and
B. B. SAUNDERS 1
1 Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439
Diethylhydroxylamine (DEHA) reacts with gas-phase hydroxyl radicals on every third collision, whereas the corresponding reaction in aqueous solution is considerably slower. The high gas-phase reactivity explains the predicted inhibitory effect of DEHA in atmospheric smog processes. Results from the studies in the aqueous phase are helpful in predicting the mechanism of the reaction of DEHA with hydroxyl radicals.
Submitted on March 21, 1977
Revised on May 16, 1977