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Science 1 October 1976:
Vol. 194. no. 4260, pp. 105 - 107
DOI: 10.1126/science.194.4260.105

Articles

Sanidine: Predicted and Observed Monoclinic-to-Triclinic Reversible Transformations at High Pressure

ROBERT M. HAZEN 1

1 Department of Mineralogy and Petrology, University of Cambridge, Cambridge CB2 3EW, England

High sanidine, (K,Na)AlSi3O8, transforms reversibly to a triclinic phase at high pressure. This is analogous to the high-temperature monalbite transformation. Disordered alkali feldspars of various compositions have unit-cell dimensions which are very similar at the transition (a = 8.30 Å, b = 12.97 Å, c = 7.14 Å, and beta = 116.2°), indicating that the transformation is structurally controlled. Changes in temperature, pressure, and the sodium/potassium ratio cause similar structural variations: angles between adjacent, rigid tetrahedra vary to accommodate changing effective alkali cation sizes.

Submitted on June 16, 1976
Revised on July 23, 1976


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