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Articles
Pyrrhotites: Synthetics Having Two New Superstructures
1 Institute of Scientific and Industrial Research, Osaka University, Yamada Kami, Suita, Osaka, Japan
Synthetic pyrrhotites Fe1-xS, synthesized at various compositions and temperatures, show the presence of two new superstructures based on the hexagonal subcell of the NiAs type (axes A and C): one, in the range 1-x=0.89 to 0.93, has a = 90A and c = 3C; the other, in the range 1 -x = 0.935 to 0.975, has a = 2A but c irrationally related to C, varying with composition.
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Science. ISSN 0036-8075 (print), 1095-9203 (online)