Zinnwaldite: Octahedral Ordering in Lithium-Iron Micas
Milan Rieder 1
1 Department of Geology, Johns Hopkins University, Baltimore, Maryland 21218
Ordering of the octahedral sheet of some lithium-iron micas is proposed on the basis of chemical compositions and crystallographic properties. The model of the ordered sheet has large and small sites in the ratio 2 : 1 and explains all observed properties the small layer thickness, the "dioctahedral reflections," and the n(120 deg) motif in polytypism.