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Articles
Crystal Structures of Titanium, Zirconium, and Hafnium at High Pressures
1 Department of the Geophysical Sciences, University of Chicago, Chicago 37, Illinois
At high pressures, as determined by x-ray analysis, titanium and zirconium metal have a distorted, body-centered-cubic structure. This phase persists on pressure release. The normal hexagonal close-packed structures are recovered when the metals are heated. An electronic shift must occur in the transition. Hafnium metal showed no such transition.
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Science. ISSN 0036-8075 (print), 1095-9203 (online)