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Published Online October 17, 2002
Science DOI: 10.1126/science.1078535

Reports

Submitted on September 18, 2002
Accepted on October 7, 2002

Superconductivity in Dense Lithium

Viktor V. Struzhkin 1*, Mikhail I. Eremets 2, Wei Gan 3, Ho-kwang Mao 1, Russell J. Hemley 1

1 Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Rd, NW, Washington, DC 20015, USA.
2 Max Planck Institut für Chemie, Postfach 3060, 55020 Mainz, Germany.
3 Geophysical Laboratory, Carnegie Institution of Washington , 5251 Broad Branch Rd, NW, Washington, DC 20015, USA; Thomas S. Wootton High School, Rockville, MD 20850, USA.

* To whom correspondence should be addressed. E-mail: struzhkin{at}gl.ciw.edu.

Superconductivity in compressed lithium is observed by magnetic susceptibility and electrical resistivity measurements. A superconducting critical temperature Tc is found ranging from 9 K to 16 K at 23 GPa to 80 GPa. The pressure dependence of Tc suggests multiple phase transitions, consistent with theoretical predictions and reported X-ray diffraction results. The observed values for Tc are much lower than those theoretically predicted indicating that more sophisticated theoretical treatments similar to those proposed for metallic hydrogen may be required to understand superconductivity in dense phases of lithium.


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