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Published Online January 3, 2002
Science DOI: 10.1126/science.1068133

Reports

Submitted on November 16, 2001
Accepted on December 14, 2001

Mapping the One-Dimensional Electronic States of Nanotube Peapod Structures

D. J. Hornbaker 1, S.-J. Kahng 2, S. Misra 1, B. W. Smith 3, A. T. Johnson 4, E. J. Mele 4, D. E. Luzzi 5, A. Yazdani 1*

1 Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA.
2 Department of Physics, Soongsil University, Seoul, Korea; Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA.
3 Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, PA 19104, USA.
4 Department of Physics and Astronomy, Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, PA 19104, USA.
5 Department of Materials Science and Engineering, Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, PA 19104, USA.

* To whom correspondence should be addressed. E-mail: ayazdani{at}uiuc.edu.

Arrays of C60 molecules nested inside single-walled nanotubes represent a class of nanoscale materials having tunable properties. We report electronic measurements of this system using a scanning tunneling microscope and demonstrate that the encapsulated C60 molecules modify the local electronic structure of the nanotube. Our measurements and calculations also show that a periodic array of C60 molecules gives rise to a hybrid electronic band, which derives its character from both the nanotube states and the C60 molecular orbitals.





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Science. ISSN 0036-8075 (print), 1095-9203 (online)