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Science 12 April 2002:
Vol. 296. no. 5566, pp. 334 - 336
DOI: 10.1126/science.1069408


Abstract
Full Text
A New Source of Basaltic Meteorites Inferred from Northwest Africa 011
Akira Yamaguchi, Robert N. Clayton, Toshiko K. Mayeda, Mitsuru Ebihara, Yasuji Oura, Yayoi N. Miura, Hiroshi Haramura, Keiji Misawa, Hideyasu Kojima, and Keisuke Nagao

Supplementary Material

Supplemental Figure 1. (A) Backscattered electron image (BEI) of a portion enriched in Ca-phosphate grains, and (B) BEI of a portion enriched in silica minerals.


Medium version | Full size version


Supplemental Table 1. Bulk chemical composition (wt%) of NWA011 determined by standard wet chemical analysis.
SiO245.63
TiO20.92
Al2O313.12
Fe2O30.15
FeO21.13
MnO0.40
MgO6.66
CaO11.11
Na2O0.45
K2O0.03
H2O(-)0.05
H2O(+)0.3
P2O5<0.02
Cr2O30.24
FeS0.05
Fe0.0
Ni0.028
Co<0.003
Total100.26


Supplemental Table 2. Abundances of 36 elements in NWA011, Juvinas, and Millbillillie.
NWA011
Juvinas
Millbillillie
Na(%)0.428±0.0540.282±0.0130.335±0.010
Mg(%)3.18±0.074.49±0.104.43±0.10
Al(%)6.09±0.066.01±0.076.69±0.08
Si(%)21.9±0.522.6±0.623.5±0.6
K(%)0.033±0.0040.031±0.0030.036±0.003
Ca(%)7.37±0797.09±0.267.22±0.31
Sc(ppm)14.3±3.333.5±0.231.0±1.4
Ti(%)0.46±0.020.47±0.010.43±0.03
V(ppm)57±467±562±5
Cr(%)0.130±0.0140.231±0.0120.230±0.011
Mn(%)0.239±0.0240.462±0.0050.465±0.018
Fe(%)17.6±0.115.6±0.115.5±0.1
Co(ppm)41.9±0.35.06±0.086.10±0.07
Ni(ppm)145±414±19±1
Zn(ppm)18±1<4<5
Ga(ppm)3.9±0.72.1±0.32.0±0.6
Se(ppm)1.9±0.5<1<1
La(ppm)0.382±0.0132.44±0.092.31±0.08
Ce(ppm)1.74±0.066.86±0.246.41±0.22
Pr(ppm)0.244±0.0081.06±0.040.983±0.033
Nd(ppm)1.09±0.045.27±0.184.85±0.16
Sm(ppm)0.462±0.0151.79±0.061.62±0.06
Eu(ppm)0.593±0.0200.565±0.0200.581±0.020
Gd(ppm)0.638±0.0222.42±0.092.17±0.07
Tb(ppm)0.136±0.0050.441±0.0160.394±0.013
Dy(ppm)1.04±0.043.06±0.112.70±0.09
Ho(ppm)0.235±0.0080.68±0.0240.602 ±0.020
Er(ppm)0.727±0.0251.96±0.071.74±0.06
Tm(ppm)0.120±0.0040.287±0.0100.255±0.009
Yb(ppm)0.837±0.0291.94±0.071.74±0.06
Lu(ppm)0.123±0.0050.296±0.0110.266±0.009
Hf(ppm)1.33±0.101.22±0.091.13±0.11
Ta(ppm)0.38±0.040.22±0.030.17±0.02
Ir(ppb)26±1<2<2
Th(ppb)18.9±2.5284±15279±16
U(ppb)25.8±4.292.4±8.189.1±7.8
*Rare Earth elements, Th, and U were determined by ICP-MS and the rest were by INAA (including PGA).


Supplemental Table 3. Cosmogenic and radiogenic noble gases of NWA011 (144 mg). Uncertainties of absolute concentrations are about 5% for He and Ne, and 10% for the others. The cosmic-ray exposure ages are calculated based on cosmogenic 3He, 21Ne, and 38Ar and their production rates given by (1, 2). Combining cosmogenic 81Kr (half life = 2.1 × 105 years) with other stable Kr isotopes, the 81Kr-Kr age is calculated from the equation: T81 = (-1/Greek Letter Lambda)(P81/P83)(83Kr/81Kr)c, where Greek Letter Lambda is the decay constant of 81Kr, (P81/P83) is the production rate ratios of cosmogenic 81Kr/83Kr, and (83Kr/81Kr)c is the cosmogenic 83Kr/81Kr ratio of the meteorite. The 81Kr-Kr dating method gives the most reliable exposure age for the meteorite with a short terrestrial age (3, 4), or an upper limit for the meteorite with a long terrestrial age (2) due to radioactive decay of 81Kr after falling on the earth (e.g., 15% decay of 81Kr corresponds to the terrestrial age of 50,000 years, which may be detectable).
Cosmogenic
(10-9cm3STP/g)
Cosmic-ray exposure age (Ma)
3He21Ne38Ar83Kr22Ne/21Ne81Kr/83KrT3T21T38T81
17649.832.50.0311.2040.0047911302339
±0.009±0.00060±5

Radiogenic
(10-9cm3STP/g)
Gas retention age (Ga)
4He40ArT40
<10045302.0
±0.3


REFERENCES

1. O. Eugster, Th. Michel, Geochim. Cosmochim. Acta 59, 177 (1995).
2. M. Freundel, L. Schultz and C. Reedy, Geochim. Cosmochim. Acta 50, 2663 (1986).
3. O. Eugster, P. Eberhardt and J. Geiss, Earth Planet. Sci. Lett. 2, 77 (1967).
4. K. Marti, Physical Rev. Lett. 18, 264 (1967).





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