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Science 12 June 2009:
Vol. 324. no. 5933, pp. 1425 - 1428
DOI: 10.1126/science.1172419

Reports

Isotopic Homojunction Band Engineering from Diamond

H. Watanabe,* C. E. Nebel,{dagger} S. Shikata

Confinement of charge carriers in semiconductors by quantum wells is usually accomplished with layers that vary in elemental composition, such as aluminum gallium arsenide and gallium arsenide. We fabricated diamond superlattices by creating multilayer structures of isotopically pure carbon isotopes carbon-12 (12C) and carbon-13 (13C), which confine electrons by a difference in band-gap energy of 17 millielectron volts. Cathodoluminescence experiments performed at 80 kelvin showed that excitonic recombination in the higher-energy band of 13C vanishes in favor of increased recombination in the lower-energy 12C material. Carrier confinement was achieved in diamond superlattices made up of both thinner (30 nanometers) and thicker (up to 350 nanometers) layers.

Diamond Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 2-13, 1-1-1, Umezono, Tsukuba, Ibaraki 305-8568, Japan.

{dagger} Present address: Fraunhofer Institut für Angewandte Festkörperphysik, Tullastrasse 72, 79108 Freiburg, Germany.

* To whom correspondence should be addressed. E-mail: hideyuki-watanabe{at}aist.go.jp

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Science. ISSN 0036-8075 (print), 1095-9203 (online)