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Science 25 November 2005:
Vol. 310. no. 5752, pp. 1307 - 1310
DOI: 10.1126/science.1118957

Reports

Super-Compressible Foamlike Carbon Nanotube Films

Anyuan Cao,1* Pamela L. Dickrell,2 W. Gregory Sawyer,2 Mehrdad N. Ghasemi-Nejhad,1 Pulickel M. Ajayan3*

We report that freestanding films of vertically aligned carbon nanotubes exhibit super-compressible foamlike behavior. Under compression, the nanotubes collectively form zigzag buckles that can fully unfold to their original length upon load release. Compared with conventional low-density flexible foams, the nanotube films show much higher compressive strength, recovery rate, and sag factor, and the open-cell nature of the nanotube arrays gives excellent breathability. The nanotube films present a class of open-cell foam structures, consisting of well-arranged one-dimensional units (nanotube struts). The lightweight, highly resilient nanotube films may be useful as compliant and energy-absorbing coatings.

1 Department of Mechanical Engineering, University of Hawaii at Manoa, Honolulu, HI 96822, USA.
2 Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611, USA.
3 Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA.

* To whom correspondence should be addressed. E-mail: anyuan{at}hawaii.edu (A.C.); ajayan{at}rpi.edu (P.M.A.)

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Science. ISSN 0036-8075 (print), 1095-9203 (online)