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Science 4 November 2005:
Vol. 310. no. 5749, p. 825
DOI: 10.1126/science.1118981
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Brevia

Synthesis and Structure of Sila-Adamantane

Jelena Fischer, Judith Baumgartner, Christoph Marschner*

An organosilicon cage compound containing the sila-adamantane structural unit, which is the building block of crystalline silicon, was synthesized by the Lewis acid-catalyzed rearrangement reaction of a structural isomer.

Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010 Graz, Austria.

* To whom correspondence should be addressed. E-mail: christoph.marschner{at}tugraz.at

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Science. ISSN 0036-8075 (print), 1095-9203 (online)