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ReportsFerroelectricity in Ultrathin Perovskite FilmsUnderstanding the suppression of ferroelectricity in perovskite thin films is a fundamental issue that has remained unresolved for decades. We report a synchrotron x-ray study of lead titanate as a function of temperature and film thickness for films as thin as a single unit cell. At room temperature, the ferroelectric phase is stable for thicknesses down to 3 unit cells (1.2 nanometers). Our results imply that no thickness limit is imposed on practical devices by an intrinsic ferroelectric size effect.
1 Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA. * To whom correspondence should be addressed. E-mail: stephenson{at}anl.gov
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Science. ISSN 0036-8075 (print), 1095-9203 (online)