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Science 3 May 2002: Vol. 296. no. 5569, pp. 892 - 895 DOI: 10.1126/science.1068054
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Reports
Ordering of Quantum Dots Using Genetically Engineered Viruses
Seung-Wuk Lee,
Chuanbin Mao,
Christine E. Flynn,
Angela M. Belcher*
A liquid crystal system was used for the fabrication of
a highly ordered composite material from genetically engineered M13 bacteriophage and zinc sulfide (ZnS) nanocrystals. The bacteriophage, which formed the basis of the self-ordering system, were selected to
have a specific recognition moiety for ZnS crystal surfaces. The
bacteriophage were coupled with ZnS solution precursors and spontaneously evolved a self-supporting hybrid film material that was
ordered at the nanoscale and at the micrometer scale into ~72-micrometer domains, which were continuous over a
centimeter length scale. In addition, suspensions were prepared in
which the lyotropic liquid crystalline phase behavior of the hybrid material was controlled by solvent concentration and by the use of a
magnetic field.
Department of Chemistry and Biochemistry, Center for Nano- and
Molecular Science and Technology, Texas Materials Institute, Institute
for Cellular and Molecular Biology, University of Texas at Austin,
Austin, TX 78712, USA.
*
Present address: Department of Materials Science and Engineering and
Biological Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
To whom correspondence should be addressed. E-mail:
belcher{at}mit.edu
Read the Full Text
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