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Ordering of Quantum Dots Using Genetically Engineered Viruses
Seung-Wuk Lee,Chuanbin Mao,Christine E. Flynn,Angela M. Belcher*
A liquid crystal system was used for the fabrication of
a highly ordered composite material from genetically engineered M13bacteriophage and zinc sulfide (ZnS) nanocrystals. The bacteriophage,which formed the basis of the self-ordering system, were selectedto
have a specific recognition moiety for ZnS crystal surfaces.The
bacteriophage were coupled with ZnS solution precursors andspontaneously evolved a self-supporting hybrid film material thatwas
ordered at the nanoscale and at the micrometer scale into~72-micrometer domains, which were continuous over a
centimeterlength scale. In addition, suspensions were prepared in
whichthe lyotropic liquid crystalline phase behavior of the hybridmaterial was controlled by solvent concentration and by the useof a
magnetic field.
Department of Chemistry and Biochemistry, Center for Nano- and
Molecular Science and Technology, Texas Materials Institute, Institute
for Cellular and Molecular Biology, University of Texas at Austin,
Austin, TX 78712, USA.
*
Present address: Department of Materials Science and Engineering and
Biological Engineering, Massachusetts Institute of Technology,Cambridge, MA 02139, USA.
To whom correspondence should be addressed. E-mail:
belcher{at}mit.edu
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[DOI: 10.1126/science.1071399] |Summary »|Full Text »|PDF »
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