High-Temperature Superconductivity in Lattice-Expanded C60
J. H. Schön,12*
Ch. Kloc,1
B. Batlogg13
C60 single crystals have been intercalated with
CHCl3 and CHBr3 in order to expand the lattice.
High densities of electrons and holes have been induced by gate doping
in a field-effect transistor geometry. At low temperatures, the
material turns superconducting with a maximum transition temperature of
117 K in hole-doped C60/CHBr3. The increasing
spacing between the C60 molecules follows the general trend of alkali metal-doped C60 and suggests routes to
even higher transition temperatures.
1 Bell Laboratories, Lucent Technologies, 600 Mountain Avenue, Murray Hill, NJ 07974, USA.
2 University of Konstanz, Department of Physics,
D-78457 Konstanz, Germany.
3 Solid State Physics
Laboratory, Eidgenössische Technische Hochschule, CH-8093
Zürich, Switzerland
*
To whom correspondence should be addressed. E-mail:
hendrik{at}lucent.com