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Science 21 April 2000: Vol. 288. no. 5465, pp. 462 - 468 DOI: 10.1126/science.288.5465.462
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Review
Orbital Physics in Transition-Metal Oxides
Y. Tokura,
12
N. Nagaosa
1
An electron in a solid, that is, bound to or nearly localized on
the specific atomic site, has three attributes: charge, spin, and
orbital. The orbital represents the shape of the electron cloud in
solid. In transition-metal oxides with anisotropic-shaped d-orbital
electrons, the Coulomb interaction between the electrons (strong
electron correlation effect) is of importance for understanding their
metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of
freedom occasionally plays an important role in these phenomena, and
its correlation and/or order-disorder transition causes a variety of
phenomena through strong coupling with charge, spin, and lattice
dynamics. An overview is given here on this "orbital physics,"
which will be a key concept for the science and technology of
correlated electrons.
1 Department of Applied Physics, University of Tokyo,
Bunkyo-ku, Tokyo 113-8656, Japan.
2 Joint Research
Center for Atom Technology, Tsukuba 305-0046, Japan.
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