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Science 21 April 2000:
Vol. 288. no. 5465, pp. 462 - 468
DOI: 10.1126/science.288.5465.462

Review

Orbital Physics in Transition-Metal Oxides

Y. Tokura, 12 N. Nagaosa 1

An electron in a solid, that is, bound to or nearly localized on the specific atomic site, has three attributes: charge, spin, and orbital. The orbital represents the shape of the electron cloud in solid. In transition-metal oxides with anisotropic-shaped d-orbital electrons, the Coulomb interaction between the electrons (strong electron correlation effect) is of importance for understanding their metal-insulator transitions and properties such as high-temperature superconductivity and colossal magnetoresistance. The orbital degree of freedom occasionally plays an important role in these phenomena, and its correlation and/or order-disorder transition causes a variety of phenomena through strong coupling with charge, spin, and lattice dynamics. An overview is given here on this "orbital physics," which will be a key concept for the science and technology of correlated electrons.

1 Department of Applied Physics, University of Tokyo, Bunkyo-ku, Tokyo 113-8656, Japan.
2 Joint Research Center for Atom Technology, Tsukuba 305-0046, Japan.


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