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Science 6 June 1997: Vol. 276. no. 5318, pp. 1533 - 1536 DOI: 10.1126/science.276.5318.1533
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Reports
Design of Surfaces for Patterned Alignment of Liquid Crystals on Planar and Curved Substrates
Vinay K. Gupta,
Nicholas L. Abbott
*
Molecularly designed surfaces formed by chemisorption of
alkanethiols on ultrathin films of gold permit control of both the azimuthal and polar orientations of supported nematic liquid crystals (LCs). These surfaces, when patterned, form simple and versatile templates for the fabrication of complex optical structures from LCs.
Surfaces patterned with odd or even alkanethiols, or mixtures of long
and short alkanethiols, were used to fabricate tunable, micrometer-scale LC diffraction gratings that differed in their polarization sensitivity. Patterned alignment of LCs on curved surfaces
is also demonstrated, thereby providing principles for fabrication of
optical elements that combine diffractive and refractive optics.
Department of Chemical Engineering and Materials Science,
University of California, Davis, CA 95616, USA.
*
To whom correspondence should be addressed. E-mail:
nlabbott{at}ucdavis.edu
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