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Science 9 June 1995:
Vol. 268. no. 5216, pp. 1466 - 1468
DOI: 10.1126/science.268.5216.1466
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Articles

Ordered Metal Nanohole Arrays Made by a Two-Step Replication of Honeycomb Structures of Anodic Alumina

Hideki Masuda 1 and Kenji Fukuda 1

1 Department of Industrial Chemistry, Faculty of Technology, Tokyo Metropolitan University, 1-1 Minamiosawa, Hachioji, Tokyo 192-03, Japan

A highly ordered metal nanohole array (platinum and gold) was fabricated by a two-step replication of the honeycomb structure of anodic porous alumina. Preparation of the negative porous structure of porous alumina followed by the formation of the positive structure with metal resulted in a honeycomb metallic structure. The metal hole array of the film has a uniform, closely packed honeycomb structure approximately 70 nanometers in diameter and from 1 to 3 micrometers thick. Because of its textured surface, the metal hole array of gold showed a notable color change compared with bulk gold.

Submitted on January 5, 1995
Accepted on April 13, 1995


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