Note to users. If you're seeing this message, it means that your browser cannot find this page's style/presentation instructions -- or possibly that you are using a browser that does not support current Web standards. Find out more about why this message is appearing, and what you can do to make your experience of our site the best it can be.


Science 23 December 1994:
Vol. 266. no. 5193, pp. 1961 - 1966
DOI: 10.1126/science.266.5193.1961

Articles

Nanomaterials: A Membrane-Based Synthetic Approach

Charles R. Martin 1

1 Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA.

Materials with nanoscopic dimensions not only have potential technological applications in areas such as device technology and drug delivery but also are of fundamental interest in that the properties of a material can change in this regime of transition between the bulk and molecular scales. In this article, a relatively new method for preparing nanomaterials, membrane-based synthesis, is reviewed. This method entails synthesis of the desired material within the pores of a nanoporous membrane. Because the membranes used contain cylindrical pores of uniform diameter, monodisperse nanocylinders of the desired material, whose dimensions can be carefully controlled, are obtained. This "template" method has been used to prepare polymers, metals, semiconductors, and other materials on a nanoscopic scale.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Aspects of Morphology Control during the Oxidative Synthesis of Electrically Conducting Polymers.
B. Schulz, B. Dietzel, I. Orgzall, I. Diez, and C. Xu (2009)
High Performance Polymers 21, 633-652
   Abstract »    PDF »
Review article: Polymer-matrix Nanocomposites, Processing, Manufacturing, and Application: An Overview.
F. Hussain, M. Hojjati, M. Okamoto, and R. E. Gorga (2006)
Journal of Composite Materials 40, 1511-1575
   Abstract »    PDF »
Highly sensitive thermoluminescent carbon doped nanoporous aluminium oxide detectors.
W. M. de Azevedo, G. B. de Oliveira, E. F. da Silva Jr, H. J. Khoury, and E. F. Oliveira de Jesus (2006)
Radiat Prot Dosimetry 119, 201-205
   Abstract »    Full Text »    PDF »
Correlating Nanoscale Titania Structure with Toxicity: A Cytotoxicity and Inflammatory Response Study with Human Dermal Fibroblasts and Human Lung Epithelial Cells.
C. M. Sayes, R. Wahi, P. A. Kurian, Y. Liu, J. L. West, K. D. Ausman, D. B. Warheit, and V. L. Colvin (2006)
Toxicol. Sci. 92, 174-185
   Abstract »    Full Text »    PDF »
On-Wire Lithography.
L. Qin, S. Park, L. Huang, and C. A. Mirkin (2005)
Science 309, 113-115
   Abstract »    Full Text »    PDF »
From The Cover: Controlled fabrication of hierarchically branched nanopores, nanotubes, and nanowires.
G. Meng, Y. J. Jung, A. Cao, R. Vajtai, and P. M. Ajayan (2005)
PNAS 102, 7074-7078
   Abstract »    Full Text »    PDF »
From The Cover: Higher-order assembly of microtubules by counterions: From hexagonal bundles to living necklaces.
D. J. Needleman, M. A. Ojeda-Lopez, U. Raviv, H. P. Miller, L. Wilson, and C. R. Safinya (2004)
PNAS 101, 16099-16103
   Abstract »    Full Text »    PDF »
DNA-Functionalized Nanotube Membranes with Single-Base Mismatch Selectivity.
P. Kohli, C. C. Harrell, Z. Cao, R. Gasparac, W. Tan, and C. R. Martin (2004)
Science 305, 984-986
   Abstract »    Full Text »    PDF »
Self-Assembly of Mesoscopic Metal-Polymer Amphiphiles.
S. Park, J.-H. Lim, S.-W. Chung, and C. A. Mirkin (2004)
Science 303, 348-351
   Abstract »    Full Text »    PDF »
Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires.
Z. Tang, N. A. Kotov, and M. Giersig (2002)
Science 297, 237-240
   Abstract »    Full Text »    PDF »
Ordered Mesoporous Polymers of Tunable Pore Size from Colloidal Silica Templates.
S. A. Johnson, P. J. Ollivier, and T. E. Mallouk (1999)
Science 283, 963-965
   Abstract »    Full Text »
A Laser Ablation Method for the Synthesis of Crystalline Semiconductor Nanowires.
A. M. Morales and C. M. Lieber (1998)
Science 279, 208-211
   Abstract »    Full Text »
Nanotubule-Based Molecular-Filtration Membranes.
K. B. Jirage, J. C. Hulteen, and C. R. Martin (1997)
Science 278, 655-658
   Abstract »    Full Text »
Nanochannel Glass Replica Membranes.
D. H. Pearson and R. J. Tonucci (1995)
Science 270, 68-70
   Abstract »    PDF »
Photodeposition of micrometer-scale polymer patterns on optical imaging fibers.
B. Healey, S. Foran, and D. Walt (1995)
Science 269, 1078-1080
   Abstract »    PDF »
Metal Nanotubule Membranes with Electrochemically Switchable Ion-Transport Selectivity.
M. Nishizawa, V. P. Menon, and C. R. Martin (1995)
Science 268, 700-702
   Abstract »    PDF »



To Advertise     Find Products


Science. ISSN 0036-8075 (print), 1095-9203 (online)