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Science 26 August 1994:
Vol. 265. no. 5176, pp. 1209 - 1212
DOI: 10.1126/science.265.5176.1209

Articles

Molecular Origins of Friction: The Force on Adsorbed Layers

Marek Cieplak 1, Elizabeth D. Smith 1, and Mark O. Robbins 1

1 Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218, USA.

Simulations and perturbation theory are used to study the molecular origins of friction in an ideal model system, a layer of adsorbed molecules sliding over a substrate. These calculations reproduce several surprising features of experimental results. In most cases, the frictional force on a solid monolayer has a different form from that observed between macroscopic solids. No threshold force or static friction is needed to initiate sliding; instead, the velocity is proportional to the force. As in experiments, incommensurate solid layers actually slide more readily than fluid layers. A comparison of experiment, simulation, and analytic results shows that dissipation arises from anharmonic coupling between phonon modes and substrate-induced deformations in the adsorbate.

Submitted on March 22, 1994
Accepted on July 11, 1994


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