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Science 19 November 1993:
Vol. 262. no. 5137, pp. 1244 - 1247
DOI: 10.1126/science.262.5137.1244

Articles

Real-Time Observation of the Vibration of a Single Adsorbed Molecule

Fumiya Watanabe 1, Gary M. McClelland 1, and Harry Heinzelmann 1

1 IBM Research Division, Almaden Research Center, San Jose, CA 95120

The newly developed femtosecond field emission camera was used to observe the time dependence of field emission through a single copper phthalocyanine molecule adsorbed on a tungsten tip. In many of the individual 212-picosecond-long recordings, the field emission was found to oscillate with a frequency between 5 x 1010 and 20 x 1010 hertz. The oscillations, which were not observed from a bare tip, are believed to arise from the vibration of a single molecule with respect to the surface. Numerical simulations confirmed the statistical significance of the data.

Submitted on July 16, 1993
Accepted on September 24, 1993





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Science. ISSN 0036-8075 (print), 1095-9203 (online)