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Science 23 July 1993:
Vol. 261. no. 5120, pp. 449 - 452
DOI: 10.1126/science.8392751

Articles

Science, Vol 261, Issue 5120, 449-452
Copyright © 1993 by American Association for the Advancement of Science


articles

Strained-layer van der Waals epitaxy in a Langmuir-Blodgett film

R Viswanathan, JA Zasadzinski, and DK Schwartz

Department of Chemical and Nuclear Engineering, University of California, Santa Barbara 93106.

Atomic force microscope images of Langmuir-Blodgett films of lead and manganese fatty acid salts show that these monolayers have long-range order and are oriented with respect to the mica substrate, although the lattice symmetries of the monolayers and substrate are dramatically different. The surface lattice of sequentially thicker films evolves toward the bulk structure while retaining the substrate alignment. This behavior is in distinct contrast to films of cadmium fatty acid salts on mica, or all films on amorphous silicon oxide, in which the monolayer structure is disordered and a three-layer-thick film displays the bulk structure.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Liquid to hexatic to crystalline order in Langmuir-Blodgett films.
R Viswanathan, L. Madsen, J. Zasadzinski, and D. Schwartz (1995)
Science 269, 51-54
   Abstract »    PDF »
Langmuir-Blodgett films.
J. Zasadzinski, R Viswanathan, L Madsen, J Garnaes, and D. Schwartz (1994)
Science 263, 1726-1733
   Abstract »    PDF »



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Science. ISSN 0036-8075 (print), 1095-9203 (online)