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Science 30 April 1993:
Vol. 260. no. 5108, pp. 647 - 649
DOI: 10.1126/science.8480175

Articles

Science, Vol 260, Issue 5108, 647-649
Copyright © 1993 by American Association for the Advancement of Science


articles

Imaging of features on surfaces by condensation figures

GP Lopez, HA Biebuyck, CD Frisbie, and GM Whitesides

Department of Chemistry, Harvard University, Cambridge, MA 02138.

Condensation of a vapor to a liquid on a cold surface that is not wet completely by this liquid leads to the formation of an array of droplets. If the surface is heterogeneous in its physical properties (especially its interfacial free energy), the patterns of these arrays reflect this heterogeneity. The distribution of droplets of water (condensation figures or CFs) observed by optical microscopy on a surface can be correlated with the molecular structure of that surface. The substrates used to investigate the formation and morphology of the CFs were patterned, self-assembled monolayers of different alkanethiolates on gold and of alkyl siloxanes on glass. Analysis of CFs is a valuable nondestructive technique for characterizing heterogeneities in surfaces.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Liquid Morphologies on Structured Surfaces: From Microchannels to Microchips.
H. Gau, S. Herminghaus, P. Lenz, and R. Lipowsky (1999)
Science 283, 46-49
   Abstract »    Full Text »
Functional Group Imaging by Chemical Force Microscopy.
C. D. Frisbie, L. F. Rozsnyai, A. Noy, M. S. Wrighton, and C. M. Lieber (1994)
Science 265, 2071-2074
   Abstract »    PDF »
Patterned Condensation Figures as Optical Diffraction Gratings.
A. Kumar and G. M. Whitesides (1994)
Science 263, 60-62
   Abstract »    PDF »



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Science. ISSN 0036-8075 (print), 1095-9203 (online)