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Articles
Fabrication and Use of Nanometer-Sized Electrodes in Electrochemistry
1 Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125
Electrodes with electrochemical dimensions as small as 10 angstroms have been fabricated and used for electrochemical studies. These nanometer-scale electrodes have enabled the measurement of electron-transfer rate constants, khet, that are two orders of magnitude faster than khet values accessible with any other electrochemical method.
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Science. ISSN 0036-8075 (print), 1095-9203 (online)