Electrides: Ionic Salts with Electrons as the Anions
James L. Dye 1
1 Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824-1322
Electrides are ionic compounds that have alkali metal cations complexed by a crown ether or cryptand, with trapped electrons as counterions. The crystal structures and properties of two electrides illustrate the diversity that is encountered. One Cs+ (18-crown-6)ze-, has relatively isolated, trapped electrons apparently centered at each anionic site. It has a low conductivity consistent with electron localization, with an activation energy for conductivity of at least 0.45 electron volt. The other, K+ (cryptand[2.2.2])e-, has electron pairs trapped in an elongated cavity in a singlet ground state, but there is also a thermally accessible paramagnetic state available. This electride is much more conducting, with an activation energy of only 0.02 electron volt.
