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ArticlesCopyright © 1989 by American Association for the Advancement of Science
Diode-laser absorption spectroscopy of supersonic carbon cluster beams: the nu 3 spectrum of C5
Department of Chemistry, University of California, Berkeley 94720, USA.
A new spectroscopic experiment has been developed in which rovibrational transitions of supersonically cooled carbon clusters, which were produced by laser vaporization of graphite, have been measured by direct-absorption diode-laser spectroscopy. Thirty-six sequential rovibrational lines of the nu 3 band of the C5 carbon cluster have been measured with Doppler-limited resolution. The absorption spectrum is characteristic of a linear molecule with a center of symmetry. Least-squares analysis of the spectrum indicates an effective carbon-carbon bond length of 1.283 angstroms, in good agreement with ab initio quantum chemical calculations. This work confirms the detection of C5 in IRC + 10216 reported in the accompanying paper.
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Science. ISSN 0036-8075 (print), 1095-9203 (online)
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