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Science 24 June 1983:
Vol. 220. no. 4604, pp. 1387 - 1389
DOI: 10.1126/science.220.4604.1387

Articles

Sex Pheromone Biosynthesis in Trichoplusia ni: Key Steps Involve Delta-11 Desaturation and Chain-Shortening

L. B. BJOSTAD 1 and W. L. ROELOFS 1

1 Department of Entomology, New York State Agricultural Experiment Station, Geneva 14456

In addition to the primary pheromone component (Z)-7-dodecenyl acetate, the sex pheromone gland of Trichoplusia ni contains the immediate fatty acyl precursor (Z)-7-dodecenoate and a large quantity of (Z)-11-hexadecenoate. Labeling experiments showed that (Z)-11-hexadecenoate is chain-shortened to (Z)-9-tetradecenoate, and that this in turn is chain-shortened to (Z)-7-dodecenoate. The same mechanism appears to explain the sex pheromone compositions of many other moth species.

Submitted on December 2, 1982
Revised on April 5, 1983


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