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Articles
Sex Pheromone Biosynthesis in Trichoplusia ni: Key Steps Involve Delta-11 Desaturation and Chain-Shortening
1 Department of Entomology, New York State Agricultural Experiment Station, Geneva 14456
In addition to the primary pheromone component (Z)-7-dodecenyl acetate, the sex pheromone gland of Trichoplusia ni contains the immediate fatty acyl precursor (Z)-7-dodecenoate and a large quantity of (Z)-11-hexadecenoate. Labeling experiments showed that (Z)-11-hexadecenoate is chain-shortened to (Z)-9-tetradecenoate, and that this in turn is chain-shortened to (Z)-7-dodecenoate. The same mechanism appears to explain the sex pheromone compositions of many other moth species. Revised on April 5, 1983
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Science. ISSN 0036-8075 (print), 1095-9203 (online)