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Science 8 February 1980:
Vol. 207. no. 4431, pp. 637 - 639
DOI: 10.1126/science.207.4431.637

Articles

Nitric Oxide in Seawater

O. C. ZAFIRIOU 1, M. MCFARLAND 2, and R. H. BROMUND 3

1 Woods Hole Oceanographic Institution, Woods Hole, Massachusetts 02543
2 National Oceanic and Atmospheric Administration Aeronomy Laboratory, Boulder, Colorado 80303
3 College of Wooster, Wooster, Ohio 44691

Nitrite photolysis at natural light intensities and normal nitrite concentrations in seawater produced detectable concentrations of nitric oxide, which was consumed rapidly by a dark chemical reaction in the laboratory. Nitric oxide was also detected in situ in nitrite-rich surface waters of the central equatorial Pacific, where it formed in daylight and disappeared rapidly at sunset. The formation and rapid cycling of nitric oxide implies the presence of other free radicals in seawater, perhaps as intermediates in ongoing autoxidation processes. The central equatorial Pacific is a nitric oxide source to the atmosphere.

Submitted on March 27, 1979
Revised on June 22, 1979


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
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Gaseous Transmission Across Time and Species.
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Integr. Comp. Biol. 41, 304-320
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Science. ISSN 0036-8075 (print), 1095-9203 (online)