Note to users. If you're seeing this message, it means that your browser cannot find this page's style/presentation instructions -- or possibly that you are using a browser that does not support current Web standards. Find out more about why this message is appearing, and what you can do to make your experience of our site the best it can be.


Science 29 November 1974:
Vol. 186. no. 4166, pp. 785 - 790
DOI: 10.1126/science.186.4166.785

Articles

Methanol as a Gasoline Extender: A Critique

E. E. Wigg 1

1 Products Research Division, Exxon Research and Engineering Company, Linden, New Jersey 07036

The tests conducted with the three vehicles at different emission control levels suggest that, in the area of fuel economy and emissions, potential benefits with methanol blends are related to carburetion and are only significant in the case of the rich-operating cars built before emission control standards were imposed. Theoretical considerations related to methanol's leaning effect on carburetion support this conclusion. Potential advantages for methanol in these areas are therefore continuously diminishing as the older cars leave the roads. At present, these older cars use only about one-fourth of the totalc motor gasoline consumed and, before methanol could be used on a large scale, this fraction would be much smaller.

The use of methanol in gasoline would almost certainly create severe product quality problems. Water contamination could lead to phase separation in the distribution system and possibly in the car tank as well, and this would require additional investment in fuel handling and blending equipment. Excess fuel volatility in hot weather may also have adverse effects on car performance if the methanol blends include typical concentrations of butanes and pentanes. Removal of these light hydrocarbon components would detract from methanol's role as a gasoline extender and if current fuel volatility specifications were maintained, its use could lead to a net loss in the total available energy for use in motor fuels. Car performance problems associated with excessively lean operation would also be expected in the case of a significant proportion of late-model cars which are adjusted to operate on lean fuel-air mixtures.

If methanol does become available in large quantities, these factors suggest that it would be more practical to use it for purposes other than those related to the extending of motor gasoline, such as for gas turbines used for electric power generation. In this case, the "pure" methanol would act as a cleanburning fuel, having none of the potentially severe product quality problems associated with its use in motor gasoline, while the fuel oil or natural gas cLirrently burned in these tuLrbines CotLild be diverted to other ulses.


THIS ARTICLE HAS BEEN CITED BY OTHER ARTICLES:
Use of Folate Analogue in Treatment of Methyl Alcohol Toxic Reactions Is Studied.
(1979)
JAMA 242, 1961-1962
   Abstract »    PDF »
Methyl Alcohol Poisoning: II. Development of a Model for Ocular Toxicity in Methyl Alcohol Poisoning Using the Rhesus Monkey.
G. Martin-Amat, T. R. Tephly, K. E. McMartin, A. B. Makar, M. S. Hayreh, S. S. Hayreh, G. Baumbach, and P. Cancilla (1977)
Arch Ophthalmol 95, 1847-1850
   Abstract »    PDF »
Hydrogen Produced from Decomposition of Methanol During Engine Compression?.
D. L. HILDEN and R. F. STEBAR (1976)
Science 192, 396-397
   PDF »



To Advertise     Find Products


Science. ISSN 0036-8075 (print), 1095-9203 (online)