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Science 27 September 1974:
Vol. 185. no. 4157, pp. 1167 - 1169
DOI: 10.1126/science.185.4157.1167

Articles

Methane Production in the Interstitial Waters of Sulfate-Depleted Marine Sediments

Christopher S. Martens 1 and Robert A. Berner 2

1 Department of Geology and Curriculum in Marine Sciences, University of North Carolina, Chapel Hill 27514
2 Department of Geology and Geophysics, Yale University, New Haven, Connecticut 06520

Methane in the interstitial waters of anoxic Long Island Sound sediments does not reach appreciable concentrations until about 90 percent of seawater sulfate is removed by sulfate-reducing bacteria. This is in agreement with laboratory studies of anoxic marine sediments sealed in jars, which indicate that methane production does not occur until dissolved sulfate is totally exhausted. Upward diffusion of methane or its production in sulfate-free microenvironments, or both, can explain the observed coexistence of measurable concentrations of methane and sulfate in the upper portions of anoxic sediments.


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