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Science 7 January 1972:
Vol. 175. no. 4017, pp. 54 - 55
DOI: 10.1126/science.175.4017.54

Articles

Atmospheric Oxygen: Isotopic Composition and Solubility Fractionation

P. Kroopnick 1 and H. Craig 2

1 Department of Oceanography, Hawaii Institute of Geophysics, University of Hawaii, Honolulu 96822
2 Scripps Institution of Oceanography, University of California, La Jolla 92037

Atmospheric oxygen has been found to be enriched in oxygen-18 by 23.5 ± 0.3 per mil relative to average ocean water (SMOW). Oxygen dissolved in seawater is further enriched in oxygen-18 by 0.85 per mil at 0°C. The temperature dependence of the solubility enrichment is given by egr (per mil) = 0.85— 0.010 t (°C). This result is in good agreement with earlier measurements of the solubility effect in distilled water.


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