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Science 16 June 1967:
Vol. 156. no. 3781, pp. 1481 - 1484
DOI: 10.1126/science.156.3781.1481
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Articles

Carbon Dioxide-Oxygen Separation: Facilitated Transport of Carbon Dioxide across a Liquid Film

William J. Ward III 1 and Walter L. Robb 2

1 General Electric Research and Development Center, Schenectady, New York 12301
2 General Electric Silicone Products Department, Waterford, New York

An immobilized film of an aqueous bicarbonate-carbonate solution was developed which was 4100 times more permeable to carbon dioxide than to oxygen. The carbon dioxide transport was reaction-rate limited, and thus it could be increased by addition to the film of catalysts for the hydrolysis of carbon dioxide.


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Science. ISSN 0036-8075 (print), 1095-9203 (online)