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Articles
Osmotic Mechanism and Negative Pressure
1 Scripps Institution of Oceanography, University of California at San Diego, La Jolla
When solute molecules are confined, they exert a positive pressure on the barrier. If this is simply the free solvent surface, balance of forces requires the solvent to attain an equal negative hydrostatic pressure. This offers a sufficient explanation for the reduction of the vapor pressure over a solution.
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Science. ISSN 0036-8075 (print), 1095-9203 (online)