Eclogitic Pyroxenes, Ordered with P2 Symmetry
Joan R. Clark 1 and
J. J. Papike 1
1 U. S. Geological Survey, Washington, D.C. 20242
X-ray diffraction crystal-structure analysis of omphacite from eclogite, Tiburon Peninsula, Marin County, California, shows that this clinopyroxene has P2 symmetry with a nearly ordered distribution of the multiple cation content defined by its approximate formula: (Nao.5 Cao.5) (Mgo.4Fe2+ 0.1 Al0.4 Fe3 +0.1) Si206. Na+ and Ca2+ tend to assume alternate locations in the structure, and ( Mg,Fe2+) octahedra alternate with Al3+. or (Al,F3+) octahedra in chains along c.